Sp2 type hybridization. Hybridization of sp2 type carbon

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Hybridization of sp-type carbon2 it occurs when it has a double bond and two single bonds or a pi bond (π) and three sigma bonds (σ). In fact, sp hybridization2 it is brought about between the atoms that establish the double bond.

An example of such a molecule is formaldehyde (CH2O). Note its structure below:

Structural formula of formaldehyde

As seen in the text "sp type hybridization3”, carbon hybridization occurs when an electron from sublevel 2s receives energy and is “transported” to the 2p sublevel and, thus, originate 4 hybridized orbitals from the "mix" of atomic orbitals pure.

In the case of formaldehyde, we know that there will be a pi bond, so one of these hybridized orbitals is reserved for this bond, while the other three perform the sigma bonds:

Carbon sp2 hybridization process

The hydrogen atoms that make the single bond with carbon, make it with their s orbital:

Bond by sp2 hybridization of hydrogen to carbon

The remaining "pure" p orbital double-bonds the oxygen atom and the formaldehyde molecule has the following structure:

Formaldehyde structural showing its orbitals

As for the type of bonds existing in this formaldehyde structure, we have:

Chemical structure of formaldehyde

Connections: 1 = 2 = σs-sp2
3 = σp-sp2
4 =πp-p


By Jennifer Fogaça
Graduated in Chemistry

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Source: Brazil School - https://brasilescola.uol.com.br/quimica/hibridizacao-tipo-sp2.htm

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