Alkynes: what they are, characteristics and nomenclature

Alkynes or alkynes are acyclic and unsaturated hydrocarbons due to the presence of a triple bond in their carbon chain.

The general formula for alkynes is: CnoH2n-2.

Features

The main characteristics of alkynes are:

  • Colorless and odorless
  • Insoluble in water
  • Soluble in organic compounds
  • Flammable
  • extremely reactive
  • Alkynes with more than 14 carbon atoms are solid.
  • Melting and boiling points are higher than those of corresponding alkenes with the same number of carbon atoms in the chain.
  • The simplest alkyne is ethyne or acetylene

Know, read also:

  • alkanes
  • alkenes
  • Cyclans
  • Alkadienes

Nomenclature

The nomenclature of alkynes follows the same rule as for other hydrocarbons:

PREFIX + INFIX + SUFFIX

The prefix indicates the amount of carbons in the main chain.

The infix is ​​given by the term "in", which represents the triple bond. The suffix is ​​given by the letter "o", which indicates the hydrocarbon compound.

Thus, the name of alkynes ends with the suffix –ino.

The main chain of an alkyne is the longest and has the triple bond. Numbering starts from the closest end of that link.

The position of the triple bond is indicated by adding a location number that precedes the alkyne and points to the carbon atom.

Examples

table row with identical HC CH end of tableEtino

table row with identical HC straight C minus cell with CH with 3 subscript end of cell end of table bribe

table row with identical HC straight C minus cell with CH with 2 subscript end of cell minus cell with CH with 3 subscript end of cell end of tableBut-1-yne or 1-butyne

table row with cell with CH with 3 subscript end of cell minus straight C identical straight C minus cell with CH with 3 subscript end of cell end of tableBut-2-yne or 2-butyne

When alkynes are branched, the branch must also be indicated:

table row with cell with CH with 3 subscript end of cell minus cell with CH with 2 subscript end of cell minus straight C identical straight C minus CH minus cell with CH with 3 subscript end of cell row with blank blank blank blank blank blank blank row vertical blank blank line with blank blank blank blank blank blank blank cell with CH with 3 subscript end of cell blank blank end of table 2-methylhex-3-yne or 2-methyl-3-hexyne

know more about:

  • Nomenclature of hydrocarbons
  • Organic compounds
  • Hydrocarbons

Application

Alkynes are not found freely in nature, so they are produced in the laboratory.

The most known and used alkyne is the acetylene or etine. It has several purposes in industries and is commonly used for the production of synthetic rubbers, textile fibers and plastics.

Acetylene is a colorless, highly combustible gas that has a pleasant smell when in its pure form.

Read too:

  • Benzene
  • Aromatic Hydrocarbons
  • Butane
  • Exercises on Hydrocarbons
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