Alkanes: what they are and nomenclature

Alkanes are hydrocarbons that have only single bonds and open chains, that is, they are saturated and acyclic.

These compounds are also called paraffinic hydrocarbons or paraffins.

The general formula for alkanes is CnoH2n+2.

Alkanes are responsible for forming oil and natural gas. They are also important fuels like cooking gas and gasoline.

Features

The main characteristics of alkanes are:

  • colorless
  • Not very reactive, as the link between C and H is quite stable
  • oil odor
  • Insoluble in water
  • Soluble in organic solvents such as ether, alcohol and benzene
  • Melting, boiling and density points increase with molecular weight

Learn more, read also:

  • alkenes
  • Alkynes
  • Cyclans
  • Alkadienes

Nomenclature

The nomenclature of alkanes is given as follows:

PREFIX + INFIX + SUFFIX

The prefix indicates the amount of carbons in the main chain.

The infix is ​​given by the term "an", which represents single links. The suffix is ​​given by the letter "o", which indicates the hydrocarbon compound.

In summary, to demonstrate that the compound is an alkane, the ending "year".

Unbranched alkanes

When the alkane chain is not branched, it is terminated YEAR.

Examples

Name

molecular formula

structural formula
Methane CH4 CH4
Ethane Ç2H6 CH3 — CH3
Propane Ç3H8 CH3 — CH2 — CH3
Butane Ç4H10 CH3 — (CH2) — CH3
pentane Ç5H12 CH3 — (CH2)3 — CH3
Hexane Ç6H12 CH3 — (CH2)4 — CH3
Heptane Ç7H16 CH3 — (CH2)5 — CH3
Octane Ç8H18 CH3 — (CH2)6 — CH3
ninth Ç9H20 CH3 — (CH2)7 — CH3
dean Ç10H22 CH3 — (CH2)8 — CH3

know more about:

  • Nomenclature of hydrocarbons
  • Organic compounds
  • Organic chemistry

branched alkanes

When dealing with branched alkanes, the branches must also be indicated.

The branches of alkanes can be simple as a result of the removal of a hydrogen atom.

The branch name is derived from the corresponding alkane, changing the suffix "year" to "il" or "ila". Hence, they are called alkyl radicals.

Examples:

Methane (CH4): If a hydrogen atom is removed, it becomes methyl (CH3).

Ethane (CH3 – CH2):With one less hydrogen atom it turns into ethyl (CH2 — CH3).

Remember that the main chain is the one with the highest number of carbons. Also, the branches should be numbered so that they are given as few as possible.

table row with cell with CH with 3 subscript end of cell minus CH minus cell with CH with 2 subscript end of cell minus cell with CH with 2 subscript end of cell minus cell with CH with 2 subscript end of cell minus cell with CH with 2 subscript end of cell minus cell with CH with 3 subscript end of cell row with blank blank vertical row blank blank blank blank blank blank blank blank blank line with blank blank CH cell with 3 subscript end of cell blank blank blank blank blank blank blank blank end of table2-methylheptane

Keep studying! Learn more about Hydrocarbons:

  • Carbon
  • Aromatic Hydrocarbons
  • Benzene
  • Butane
  • Petroleum
  • Exercises on Hydrocarbons
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