What is hydrated salt?

hydrated salt it is a salt in which the ions of the compound incorporate water molecules into their crystalline lattices, which makes these molecules become part of the salt crystal.

Representation of the crystalline lattice of a salt
Representation of the crystalline lattice of a salt

The chemical formula of a hydrated salt follows a pattern, in which we have the presence of any cation (X+), any anion (Y-) and a certain amount (n) in moles of water, as can be seen in the following model:

XY.nH2O

To form the nomenclature of a hydrated salt, we must carry out the following rules:

Anion name + de + cation name + prefix + hydrated

Note: The prefix indicated in the nomenclature rule refers to the amount in mol of water present in the salt formula, thus, for 1 mol (mono), 2 mol (d), 3 mol (tri), etc.

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1st Example: FeCl2.2.H2O

This hydrated salt has the following components:

  • Iron cation II (Fe+2);

  • Chloride anion (Cl-);

  • 2 moles of H2O (prefix di).

So its name will be iron II chloride dihydrate.

2nd Example: MgSO44.7.H2O

This hydrated salt has the following components:

  • Magnesium Cation (Mg+2);

  • Sulfate anion (SO4-2);

  • 7 mol of H2O (prefix hepta).

So its name will be magnesium sulfate heptahydrate.

3rd Example: ZnBr2.8.H2O

This hydrated salt has the following components:

  • Zinc cation (Zn+2);

  • Bromide anion (Br-1);

  • 8 mol of H2O (prefix octa).

So its name will be zinc bromide octahydrate.

chemical modification

When a hydrated salt undergoes a heating process, the water molecules incorporated into the crystalline structure are released in the form of vapor, leaving only a simple salt.


By Me. Diogo Lopes

Would you like to reference this text in a school or academic work? Look:

DAYS, Diogo Lopes. "What is hydrated salt?"; Brazil School. Available in: https://brasilescola.uol.com.br/o-que-e/quimica/o-que-e-sal-hidratado.htm. Accessed on June 27, 2021.

Nomenclature of Salts

Salt nomenclature, salt classification, anion name, cation name, iron sulfate, ferrous sulfate, nitrate of silver, potassium chloride, sodium chloride, calcium chloride, silver nitrate, copper sulfate, carbonate calcium.

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