TNT – Trinitrotoluene. TNT and its use as an explosive

The acronym TNT stands for trinitrotoluene. It is a nitro compound and its chemical name is 2-methyl-1,3,5-trinitrobenzene. Its formula is shown below:

Structural formula of TNT (trinitrotoluene or 2-methyl-1,3,5-trinitrobenzene).

It is a yellow crystalline solid that has a high explosive potential. TNT is so explosive that it detonates with just a temperature of 80°C or an electrical spark. This is because in its structure there are enough oxygen atoms for combustion to take place.

The method for obtaining trinitrotoluene is the total nitration of toluene, that is, when toluene reacts with nitric acid (HNO3). This total nitration means that nitrations will be made until all possible replacements are made. In the case of toluene, a maximum of three substitutions in the nucleus of the benzene ring are possible: two in ortho and one in para. Let's look at this replacement reaction below:

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Nitration reaction to obtain TNT

TNT, as well as tretyl explosives (N-methyl-2,4,6-trinitrophenyl-nitramine) and RDX (Cyclotrimethylenetrinitro-amine), was invented at the beginning of the 20th century, mainly due to the First World War.

Despite being often used as a weapon, its peaceful use is also very extensive. Plastic explosives, for example, often used in building implosions and other buildings, are actually TNT itself interconnected to a device. This device emits an electrical spark when activated, which causes the TNT to explode.

TNT is widely used in implosions

By Jennifer Fogaça
Graduated in Chemistry
Brazil School Team

Would you like to reference this text in a school or academic work? Look:

FOGAÇA, Jennifer Rocha Vargas. "TNT - Trinitrotoluene"; Brazil School. Available in: https://brasilescola.uol.com.br/quimica/tnt-trinitrotolueno.htm. Accessed on June 28, 2021.

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