Classification of acids. Acid classification criteria

Acids are closely related to people's daily lives, whether in the professional or personal field. Its general characteristics are sour taste, liquid state and water ionization. These aspects are closely related to the classification of these substances, so it is very important to know it.

Classification of acids involves a wide range of criteria. Are they:

  • Volatility;

  • Stability;

  • Degree of oxygenation;

  • Hydration degree;

  • Number of ionizable hydrogens;

  • Strength.

a) Volatility

Volatility is the term used to say that a certain liquid material is easily transferred to the gaseous state because it has a low boiling point. In relation to this criterion, acids are classified as follows:

  • volatiles: acids with a low boiling point that easily change to a gaseous state.
    Examples: HCl, HBr and HClO4.

  • Fixed: acids with high boiling points which, therefore, do not easily pass into the gaseous state.
    Examples: H3DUST4, H2ONLY4 and H3BO3.

b) Stability

The term stability refers to the ability of a substance not to decompose, that is, not to spontaneously transform into other substances. In relation to this criterion, acids are classified as follows:

  • stable: acids that do not decompose under ambient conditions.
    Examples: HCl, HIO4, H2ONLY4,...

  • Unstable: acids that decompose under ambient conditions.
    Examples: H2CO3, H2s2O3 and H2ONLY3.

c) Degree of oxygenation

This criterion involves the presence or absence of oxygen in the composition of acids. Therefore, acids can be classified into:

  • Hidracids: acids that do not have oxygen in their composition. Examples: HI, HCN and H2S.

  • oxyacids: acids that have oxygen in their composition. Examples: H3DUST3, H2ONLY3 and HBrO2.

d) Degree of hydration

Indicates the removal of water molecules from the formula of an acid so that it originates a new oxyacid. According to this criterion, acids can be classified into:

  • meta acid: it has the lowest degree of hydration that an acid can have. It originates from the loss of a water molecule by an acid ortho.
    Example: HPO3. the HPO3 is a meta acid in that the ortho H acid3DUST4, when losing a water molecule (H2O) becomes the goal.

  • Pyro acid: it has an amount of water greater than that of the meta and less than that of the ortho. It originates when we multiply an ortho acid by 2 and then take a molecule out of water.
    Example: H4P2O7. the H4P2O7 is a pyro acid because when we multiply its ortho (H3DUST4) for two, we have the H molecule6P2O8 . When removing the water molecule, we have the H4P2O7.

  • ortho acid: it has the highest degree of hydration that an acid can have. It is always a common acid that has a sufficient number of hydrogens and oxygens to allow the removal of a water molecule.
    Example: H3DUST4.

e) Number of ionizable hydrogens

According to the amount of hydrogens that can undergo ionization when added to water, acids can be classified as follows:

  • monoacid: features an ionizable hydrogen. Example: HI.

  • diacid: features two ionizable hydrogens. Example: H2ONLY3.

  • Triacid: features three ionizable hydrogens. Example: H3BO3.

  • tetracid: features four ionizable hydrogens. Example: H4P2O7.

f) Strength

The strength of an acid is related to its ability to ionize a lot, a little or a fair amount. Regarding these criteria, acids are classified into:

  • strong: acids that ionize a lot. Examples: H4P2O7, H2ONLY4, HCl and HBr.

  • moderateorsemi-strong: acids that ionize reasonably, that is, more than a weak and less than a strong. Examples: H2ONLY3, H2s2O3 and HF.

  • weak: acids that are poorly ionized. Examples: HClO, H3BO3, HCN and H2S.


By Me. Diogo Lopes Dias

Source: Brazil School - https://brasilescola.uol.com.br/quimica/classificacao-dos-acidos.htm

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